Information card for entry 7027390

Structure parameters

• Formula: C26 H46 F6 P3 Rh
• Calculated formula: C26 H46 F6 P3 Rh
• SMILES: [Rh]123456([P](C[P]1(C1CCCCC1)C1CCCCC1)(C(C)C)C(C)C)[c]1([cH]2[cH]3[cH]4[cH]5[cH]61)C.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: A new synthetic route to ligands of the general composition R2PCH2ER′2 (E = P, As) and some rhodium complexes derived thereof
• Authors of publication: Wolf, Justin; Manger, Matthias; Schmidt, Ulrich; Fries, Guido; Barth, Dietmar; Weberndörfer, Birgit; Vicic, David A.; Jones, William D.; Werner, Helmut
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 11
• Pages of publication: 1867
• a: 18.8181 ± 0.0006 Å
• b: 10.8572 ± 0.0003 Å
• c: 29.2564 ± 0.001 Å
• α: 90°
• β: 96.791 ± 0.001°
• γ: 90°
• Cell volume: 5935.5 ± 0.3 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 5
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0673
• Residual factor for significantly intense reflections: 0.0537
• Weighted residual factors for all reflections: 0.1142
• Weighted residual factors for significantly intense reflections: 0.106
• Goodness-of-fit parameter for all reflections: 1.139
• Goodness-of-fit parameter for significantly intense reflections: 1.162
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No