Information card for entry 7027433

Structure parameters

• Formula: C14 H2 As F3 O13 Ru4
• Calculated formula: C14 H2 As F3 O13 Ru4
• SMILES: [Ru]1234(C#[O])(C#[O])(C#[O])[H][Ru]456(C#[O])(C#[O])(C#[O])[H][Ru]26(C#[O])(C#[O])(C#[O])[As]35([Ru]1(C#[O])(C#[O])(C#[O])C#[O])C(F)(F)F
• Title of publication: Reactions of trifluoromethyl-phosphine and -arsine with a ruthenium carbonyl cluster: synthesis, characterization and reactivity of cluster derivatives capped by trifluoromethyl-phosphinidene and -arsinidene moieties
• Authors of publication: Ang, How Ghee; Ang, Siau Gek; Du, Shaowu; Sow, Boon Hwa; Wu, Xintao
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 16
• Pages of publication: 2799
• a: 17.3431 ± 0.0002 Å
• b: 15.4671 ± 0.0001 Å
• c: 18.0049 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4829.77 ± 0.08 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0375
• Residual factor for significantly intense reflections: 0.0252
• Weighted residual factors for all reflections: 0.0498
• Weighted residual factors for significantly intense reflections: 0.0448
• Goodness-of-fit parameter for all reflections: 1.13
• Goodness-of-fit parameter for significantly intense reflections: 1.13
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No