Information card for entry 7027540

Structure parameters

• Formula: C42 H36 Cl10 O4 P2 Rh2
• Calculated formula: C42 H36 Cl10 O4 P2 Rh2
• SMILES: [Rh]123([Rh]4(Cl)([O]=C(C)O1)([O]=C(C)O2)[P](c1ccccc1)(c1ccccc1)c1ccccc1[Cl]4)(Cl)[P](c1ccccc1)(c1ccccc1)c1ccccc1[Cl]3.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl
• Title of publication: A new structural type of dinuclear rhodium(II) compounds: synthesis by serendipity and design; catalytic behaviour in carbene transfer reactions †
• Authors of publication: Estevan, Francisco; García-Bernabé, Abel; García-Granda, Santiago; Lahuerta, Pascual; Moreno, Eduardo; Pérez-Prieto, Julia; Sanaú, Mercedes; Ubeda, M. Angeles
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 19
• Pages of publication: 3493
• a: 13.398 ± 0.006 Å
• b: 13.623 ± 0.005 Å
• c: 14.538 ± 0.005 Å
• α: 77.4 ± 0.05°
• β: 84.25 ± 0.05°
• γ: 69.69 ± 0.04°
• Cell volume: 2427.7 ± 1.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 290 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0587
• Residual factor for significantly intense reflections: 0.0352
• Weighted residual factors for significantly intense reflections: 0.0947
• Weighted residual factors for all reflections included in the refinement: 0.1041
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No