Information card for entry 7027786

Structure parameters

• Formula: C14 H28 Cl Mg O P
• Calculated formula: C7 H14 Cl0.5 Mg0.5 O0.5 P0.5
• Title of publication: A convenient synthetic route to substituted phosphavinyl Grignard reagents: synthesis and characterisation of [{RPC(But)MgX(OEt2)}2] (R = cyclohexyl, cyclopentyl, ethyl or mesityl; X = Cl or Br) †
• Authors of publication: Hibbs, David E.; Jones, Cameron; Richards, Anne F.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1999
• Journal issue: 20
• Pages of publication: 3531
• a: 8.162 ± 0.009 Å
• b: 9.682 ± 0.007 Å
• c: 12.341 ± 0.01 Å
• α: 70.69 ± 0.02°
• β: 75.44 ± 0.018°
• γ: 78.995 ± 0.016°
• Cell volume: 884.6 ± 1.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0388
• Residual factor for significantly intense reflections: 0.0346
• Weighted residual factors for significantly intense reflections: 0.0951
• Weighted residual factors for all reflections included in the refinement: 0.0972
• Goodness-of-fit parameter for all reflections included in the refinement: 1.074
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No