Information card for entry 7028058

Structure parameters

• Chemical name: Bis(3-Me-boryl)bis(triphenylphosphine)Rhodium(III)Chloride
• Formula: C56 H55 B2 Cl7 O4 P2 Rh
• Calculated formula: C55 H48 B2 Cl7 O4 P2 Rh
• Title of publication: Boron‒boron bond oxidative addition to rhodium(I) and iridium(I) centres
• Authors of publication: Clegg, William; Lawlor, Fiona J.; Marder, Todd B.; Nguyen, Paul; Norman, Nicholas C.; Orpen, A. Guy; Quayle, Michael J.; Rice, Craig R.; Robins, Edward G.; Scott, Andrew J.; Souza, Fabio E. S.; Stringer, Graham; Whittell, George R.
• Journal of publication: Journal of the Chemical Society, Dalton Transactions
• Year of publication: 1998
• Journal issue: 2
• Pages of publication: 301
• a: 10.939 ± 0.004 Å
• b: 13.843 ± 0.006 Å
• c: 19.916 ± 0.007 Å
• α: 80.34 ± 0.03°
• β: 81.99 ± 0.03°
• γ: 77.63 ± 0.03°
• Cell volume: 2887 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.2386
• Residual factor for significantly intense reflections: 0.1083
• Weighted residual factors for all reflections: 0.3042
• Weighted residual factors for significantly intense reflections: 0.2459
• Goodness-of-fit parameter for all reflections: 0.899
• Goodness-of-fit parameter for significantly intense reflections: 1.248
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No