Information card for entry 7029777

Structure parameters

• Formula: C96 H130 Li4 N6 O2 P2 Si2
• Calculated formula: C96 H130 Li4 N6 O2 P2 Si2
• SMILES: [P]1(N([Si]([O]23[Li]41[O]15[Si](N([P]([Li]35[N]3([Li]2[N](=C[N]4([Li]1[N](=C3)C1CCCCC1)C1CCCCC1)C1CCCCC1)C1CCCCC1)(c1ccccc1)c1ccccc1)c1c(cccc1C(C)C)C(C)C)(C)C)(C)C)c1c(cccc1C(C)C)C(C)C)(c1ccccc1)c1ccccc1.c1ccccc1.c1ccccc1.c1ccccc1
• Title of publication: Reactivity studies of a soluble LiH-complex and non-spectator behaviour of its stabilising phosphinoamide ligand.
• Authors of publication: Stasch, Andreas
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 19
• Pages of publication: 7078 - 7086
• a: 14.003 ± 0.003 Å
• b: 22.742 ± 0.005 Å
• c: 28.741 ± 0.006 Å
• α: 90°
• β: 94.69 ± 0.03°
• γ: 90°
• Cell volume: 9122 ± 3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0774
• Residual factor for significantly intense reflections: 0.0652
• Weighted residual factors for significantly intense reflections: 0.172
• Weighted residual factors for all reflections included in the refinement: 0.1827
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.7101 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No