Steric effects caused by N-alkylation of the tripodal chelator N,N′,N″-tris(2-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane (tachpyr): structural and electronic properties of the Mn(ii), Co(ii), Ni(ii), Cu(ii) and Zn(ii) complexes
Authors of publication
Park, Gyungse; Przyborowska, Ann M.; Ye, Neng; Tsoupas, Nicole M.; Bauer, Cary B.; Broker, Grant A.; Rogers, Robin D.; Brechbiel, Martin W.; Planalp, Roy P.
Journal of publication
Dalton Transactions
Year of publication
2003
Journal issue
3
Pages of publication
318
a
13.4196 ± 0.0002 Å
b
13.8089 ± 0.0001 Å
c
15.2639 ± 0.0001 Å
α
90°
β
110.406 ± 0.001°
γ
90°
Cell volume
2651.05 ± 0.05 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0485
Residual factor for significantly intense reflections
0.0392
Weighted residual factors for significantly intense reflections
0.1093
Weighted residual factors for all reflections included in the refinement
0.1144
Goodness-of-fit parameter for all reflections included in the refinement
