Steric effects caused by N-alkylation of the tripodal chelator N,N′,N″-tris(2-pyridylmethyl)-cis,cis-1,3,5-triaminocyclohexane (tachpyr): structural and electronic properties of the Mn(ii), Co(ii), Ni(ii), Cu(ii) and Zn(ii) complexes
Authors of publication
Park, Gyungse; Przyborowska, Ann M.; Ye, Neng; Tsoupas, Nicole M.; Bauer, Cary B.; Broker, Grant A.; Rogers, Robin D.; Brechbiel, Martin W.; Planalp, Roy P.
Journal of publication
Dalton Transactions
Year of publication
2003
Journal issue
3
Pages of publication
318
a
9.4103 ± 0.0002 Å
b
14.5893 ± 0.0003 Å
c
19.1238 ± 0.0004 Å
α
90°
β
94.318 ± 0.001°
γ
90°
Cell volume
2618.05 ± 0.09 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0619
Residual factor for significantly intense reflections
0.0581
Weighted residual factors for all reflections
0.1938
Weighted residual factors for significantly intense reflections
0.1849
Goodness-of-fit parameter for all reflections
1.101
Goodness-of-fit parameter for significantly intense reflections
