Information card for entry 7031810

Structure parameters

• Common name: [Au(CS2N3)2]AsPh4
• Formula: C26 H20 As Au N6 S4
• Calculated formula: C26 H20 As Au N6 S4
• Title of publication: Formation and structure of two luminescent salts of [Au(SCSN3)2](-) obtained through the [2 + 3] cyclization of carbon disulfide and azide ion.
• Authors of publication: Lim, Sang Ho; Schmitt, Jennifer C.; Shearer, Jason; England, Kellie R.; Olmstead, Marilyn M.; Balch, Alan L.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2014
• Journal volume: 43
• Journal issue: 36
• Pages of publication: 13756 - 13763
• a: 12.5645 ± 0.0004 Å
• b: 7.0981 ± 0.0002 Å
• c: 33.1512 ± 0.001 Å
• α: 90°
• β: 110.023 ± 0.001°
• γ: 90°
• Cell volume: 2777.85 ± 0.15 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0375
• Residual factor for significantly intense reflections: 0.0253
• Weighted residual factors for significantly intense reflections: 0.0488
• Weighted residual factors for all reflections included in the refinement: 0.0519
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No