Information card for entry 7033525

Structure parameters

• Formula: C42 H87 N8 P4 Rh Te5
• Calculated formula: C42 H87 N8 P4 Rh Te5
• SMILES: [Te]1[Te]2([Te]P3(N(C(C)(C)C)P1(=NC(C)(C)C)N3C(C)(C)C)=NC(C)(C)C)[Te]1[Rh]34562([Te]P2(N(C(C)(C)C)P1(=NC(C)(C)C)N2C(C)(C)C)=NC(C)(C)C)[c]1([c]6([c]5([c]4([c]31C)C)C)C)C
• Title of publication: Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings.
• Authors of publication: Nordheider, Andreas; Athukorala Arachchige, Kasun S.; Slawin, Alexandra M. Z.; Woollins, J. Derek; Chivers, Tristram
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 19
• Pages of publication: 8781 - 8783
• a: 15.98 ± 0.003 Å
• b: 19.756 ± 0.004 Å
• c: 18.904 ± 0.004 Å
• α: 90°
• β: 95.606 ± 0.004°
• γ: 90°
• Cell volume: 5939 ± 2 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.049
• Weighted residual factors for all reflections included in the refinement: 0.1352
• Goodness-of-fit parameter for all reflections included in the refinement: 0.979
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No