Metallacyclic yttrium alkyl and hydrido complexes: synthesis, structures and catalytic activity in intermolecular olefin hydrophosphination and hydroamination.
Authors of publication
Kissel, Alexander A.; Mahrova, Tatyana V.; Lyubov, Dmitry M.; Cherkasov, Anton V.; Fukin, Georgy K.; Trifonov, Alexander A.; Del Rosal, Iker; Maron, Laurent
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2015
Journal volume
44
Journal issue
27
Pages of publication
12137 - 12148
a
16.5905 ± 0.0007 Å
b
16.5905 ± 0.0007 Å
c
74.717 ± 0.003 Å
α
90°
β
90°
γ
120°
Cell volume
17810.2 ± 1.3 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
6
Space group number
161
Hermann-Mauguin space group symbol
R 3 c :H
Hall space group symbol
R 3 -2"c
Residual factor for all reflections
0.081
Residual factor for significantly intense reflections
0.0657
Weighted residual factors for significantly intense reflections
0.167
Weighted residual factors for all reflections included in the refinement
0.1766
Goodness-of-fit parameter for all reflections included in the refinement
