Information card for entry 7035927

Structure parameters

• Formula: C47 H41 Cl3 N P Si
• Calculated formula: C47 H41 Cl3 N P Si
• SMILES: Cl[Si](Cl)(Cl)N(P(c1ccccc1)c1ccccc1)c1c(C(c2ccccc2)c2ccccc2)cc(cc1C(c1ccccc1)c1ccccc1)C(C)C
• Title of publication: Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes.
• Authors of publication: Böttcher, Tobias; Jones, Cameron
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2015
• Journal volume: 44
• Journal issue: 33
• Pages of publication: 14842 - 14853
• a: 10.0456 ± 0.0015 Å
• b: 13.252 ± 0.002 Å
• c: 29.583 ± 0.007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3938.2 ± 1.3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.1549
• Residual factor for significantly intense reflections: 0.1039
• Weighted residual factors for significantly intense reflections: 0.241
• Weighted residual factors for all reflections included in the refinement: 0.2826
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No