Information card for entry 7036089

Structure parameters

• Chemical name: bis(tertbutyldimethylsilyl)amido magnesium chloride
• Formula: C32 H76 Cl2 Mg2 N2 O2 Si4
• Calculated formula: C32 H76 Cl2 Mg2 N2 O2 Si4
• SMILES: C(C)([Si](C)(C)N([Mg]1([Cl][Mg](N([Si](C(C)(C)C)(C)C)[Si](C(C)(C)C)(C)C)([O]2CCCC2)[Cl]1)[O]1CCCC1)[Si](C(C)(C)C)(C)C)(C)C
• Title of publication: Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
• Authors of publication: Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6004 - 6014
• a: 9.5683 ± 0.0007 Å
• b: 11.3302 ± 0.0015 Å
• c: 21.3284 ± 0.0019 Å
• α: 90°
• β: 99.871 ± 0.008°
• γ: 90°
• Cell volume: 2278 ± 0.4 ų
• Cell temperature: 150.03 ± 0.1 K
• Ambient diffraction temperature: 150.03 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1373
• Residual factor for significantly intense reflections: 0.0738
• Weighted residual factors for significantly intense reflections: 0.1504
• Weighted residual factors for all reflections included in the refinement: 0.1969
• Goodness-of-fit parameter for all reflections included in the refinement: 1.021
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No