Information card for entry 7036090

Structure parameters

• Formula: C38 H88 Cl2 Mg2 N2 O2 Si4
• Calculated formula: C38 H88 Cl2 Mg2 N2 O2 Si4
• SMILES: CC(C)(C)[Si](N([Mg]1([Cl][Mg](N([Si](C(C)C)(C(C)C)C(C)C)[Si](C(C)(C)C)(C)C)([O]2CCCC2)[Cl]1)[O]1CCCC1)[Si](C(C)C)(C(C)C)C(C)C)(C)C
• Title of publication: Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
• Authors of publication: Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6004 - 6014
• a: 9.7845 ± 0.0008 Å
• b: 11.0265 ± 0.0011 Å
• c: 12.2422 ± 0.0012 Å
• α: 86.179 ± 0.008°
• β: 88.328 ± 0.008°
• γ: 67.12 ± 0.009°
• Cell volume: 1214.2 ± 0.2 ų
• Cell temperature: 108 ± 2 K
• Ambient diffraction temperature: 108.2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0749
• Residual factor for significantly intense reflections: 0.051
• Weighted residual factors for significantly intense reflections: 0.1029
• Weighted residual factors for all reflections included in the refinement: 0.1172
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No