Information card for entry 7036095

Structure parameters

• Formula: C26 H66 Mg2 N2 Si4
• Calculated formula: C26 H66 Mg2 N2 Si4
• SMILES: [Mg]1(N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[CH3][Mg](N([Si](C)(C)C(C)(C)C)[Si](C)(C)C(C)(C)C)[CH3]1
• Title of publication: Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes.
• Authors of publication: Goodwin, Conrad A. P.; Smith, Alex; Ortu, Fabrizio; Vitorica-Yrezabal, Iñigo J; Mills, David P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 14
• Pages of publication: 6004 - 6014
• a: 7.7791 ± 0.0008 Å
• b: 9.64 ± 0.0009 Å
• c: 13.4373 ± 0.0011 Å
• α: 94.746 ± 0.007°
• β: 94.148 ± 0.007°
• γ: 109.082 ± 0.009°
• Cell volume: 943.74 ± 0.16 ų
• Cell temperature: 150.01 ± 0.11 K
• Ambient diffraction temperature: 150.01 ± 0.11 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1128
• Residual factor for significantly intense reflections: 0.0648
• Weighted residual factors for significantly intense reflections: 0.1175
• Weighted residual factors for all reflections included in the refinement: 0.1416
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No