Information card for entry 7037445

Structure parameters

• Formula: C24 H29 Cl N2 P Rh
• Calculated formula: C24 H29 Cl N2 P Rh
• SMILES: [Rh]123(Cl)([P]4(C(=Nc5c4nccc5)C(C)(C)C)c4ccccc4)[CH]4=[CH]1CC[CH]2=[CH]3CC4
• Title of publication: 3H-1,3-Azaphospholo[4,5-b]pyridines - novel heterocyclic P,N-bridging or hybrid ligands: synthesis and first d(8)-transition metal complexes.
• Authors of publication: Adam, Mohamed Shaker S.; Kindermann, Markus K.; Jones, Peter G.; Heinicke, Joachim W.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 5
• Pages of publication: 2261 - 2272
• a: 9.1441 ± 0.0006 Å
• b: 9.8885 ± 0.0006 Å
• c: 13.5572 ± 0.0008 Å
• α: 83.875 ± 0.002°
• β: 81.588 ± 0.002°
• γ: 67.831 ± 0.003°
• Cell volume: 1121.25 ± 0.12 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0176
• Residual factor for significantly intense reflections: 0.0166
• Weighted residual factors for significantly intense reflections: 0.0422
• Weighted residual factors for all reflections included in the refinement: 0.0429
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No