Information card for entry 7037814

Structure parameters

• Formula: C110 H92 Cl16 N4 O6 P4 Pt6 Sn6
• Calculated formula: C110 H92 Cl16 N4 O6 P4 Pt6 Sn6
• SMILES: C(#[O])[Pt]12345[Pt]6789%10%11(C#[O])[Sn]%121(Cl)(Cl)[Pt]1%13%14%1538(C#[O])[Pt]387(C#[O])([Pt]%10%12%13(C#[O])([Sn]%153(Cl)(Cl)Cl)[Sn]8(Cl)(Cl)Cl)[Sn]%11%14(Cl)(Cl)[Pt]491([Sn]26(Cl)(Cl)Cl)(C#[O])[Sn]5(Cl)(Cl)Cl.N#CC.N#CC.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.N#CC.N#CC.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Platinum carbonyl clusters stabilized by Sn(ii)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.).
• Authors of publication: Bortoluzzi, Marco; Ceriotti, Alessandro; Ciabatti, Iacopo; Della Pergola, Roberto; Femoni, Cristina; Carmela Iapalucci, Maria; Storione, Alba; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 12
• Pages of publication: 5001 - 5013
• a: 13.0696 ± 0.0005 Å
• b: 18.9114 ± 0.0007 Å
• c: 26.3812 ± 0.001 Å
• α: 90°
• β: 91.697 ± 0.002°
• γ: 90°
• Cell volume: 6517.6 ± 0.4 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0702
• Residual factor for significantly intense reflections: 0.0399
• Weighted residual factors for significantly intense reflections: 0.0855
• Weighted residual factors for all reflections included in the refinement: 0.1038
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No