Information card for entry 7037815

Structure parameters

• Formula: C110 H92 Cl16 N4 O6 P4 Pt6 Sn6
• Calculated formula: C110 H92 Cl16 N4 O6 P4 Pt6 Sn6
• SMILES: C(#[O])[Pt]1234567[Pt]89%10%11([Pt]%12%131(C#[O])([Sn]8(Cl)(Cl)Cl)[Sn]13(Cl)(Cl)[Pt]3849%12(C#[O])([Pt]4951([Sn]2(Cl)(Cl)(Cl)[Pt]634(C#[O])([Sn]9(Cl)(Cl)Cl)[Sn]7%118(Cl)Cl)C#[O])[Sn]%10%13(Cl)(Cl)Cl)C#[O].N#CC.N#CC.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.N#CC.N#CC.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Platinum carbonyl clusters stabilized by Sn(ii)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.).
• Authors of publication: Bortoluzzi, Marco; Ceriotti, Alessandro; Ciabatti, Iacopo; Della Pergola, Roberto; Femoni, Cristina; Carmela Iapalucci, Maria; Storione, Alba; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 12
• Pages of publication: 5001 - 5013
• a: 13.707 ± 0.007 Å
• b: 28.016 ± 0.014 Å
• c: 17.266 ± 0.009 Å
• α: 90°
• β: 92.377 ± 0.006°
• γ: 90°
• Cell volume: 6625 ± 6 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0493
• Residual factor for significantly intense reflections: 0.0383
• Weighted residual factors for significantly intense reflections: 0.0959
• Weighted residual factors for all reflections included in the refinement: 0.1019
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No