Information card for entry 7037817

Structure parameters

• Formula: C54 H52 Cl14 O2 P2 Pt Sn5
• Calculated formula: C54 H52 Cl14 O2 P2 Pt Sn5
• SMILES: C(C)(C)=[O][Sn](Cl)([Pt]([Sn](Cl)(Cl)Cl)([Sn](Cl)(Cl)Cl)([Sn](Cl)(Cl)Cl)[Sn](Cl)(Cl)Cl)([O]=C(C)C)Cl.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Platinum carbonyl clusters stabilized by Sn(ii)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.).
• Authors of publication: Bortoluzzi, Marco; Ceriotti, Alessandro; Ciabatti, Iacopo; Della Pergola, Roberto; Femoni, Cristina; Carmela Iapalucci, Maria; Storione, Alba; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 12
• Pages of publication: 5001 - 5013
• a: 20.3822 ± 0.0007 Å
• b: 14.5461 ± 0.0005 Å
• c: 26.2602 ± 0.0011 Å
• α: 90°
• β: 112.334 ± 0.002°
• γ: 90°
• Cell volume: 7201.6 ± 0.5 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0741
• Residual factor for significantly intense reflections: 0.0472
• Weighted residual factors for significantly intense reflections: 0.1013
• Weighted residual factors for all reflections included in the refinement: 0.1129
• Goodness-of-fit parameter for all reflections included in the refinement: 1.076
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No