Information card for entry 7037816

Structure parameters

• Formula: C70 H58 Cl8 O18 P2 Pt10 Sn4
• Calculated formula: C70 H58 Cl8 O18 P2 Pt10 Sn4
• SMILES: C(#[O])[Pt]123456C(=O)[Pt]789%101([Sn]1%11([OH][Sn]%122(Cl)(Cl)[Pt]2%13%14%15371(C#[O])[Pt]137%16%17(C#[O])C(=O)[Pt]%18%19%20%15%16(C#[O])[Pt]%15%16%214821(C#[O])[Pt]15%18(C(=O)[Pt]6%12%14%191C#[O])(C#[O])[Sn]%20%16([OH][Sn]%17%21(Cl)(Cl)[Pt]1%107%15(C(=O)[Pt]9%11%1331C#[O])C#[O])(Cl)Cl)(Cl)Cl)C#[O].[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.C1CCCO1.[P+](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.C1CCCO1
• Title of publication: Platinum carbonyl clusters stabilized by Sn(ii)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.).
• Authors of publication: Bortoluzzi, Marco; Ceriotti, Alessandro; Ciabatti, Iacopo; Della Pergola, Roberto; Femoni, Cristina; Carmela Iapalucci, Maria; Storione, Alba; Zacchini, Stefano
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 12
• Pages of publication: 5001 - 5013
• a: 12.596 ± 0.004 Å
• b: 18.116 ± 0.005 Å
• c: 20.422 ± 0.006 Å
• α: 90°
• β: 103.388 ± 0.003°
• γ: 90°
• Cell volume: 4533 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1667
• Residual factor for significantly intense reflections: 0.0997
• Weighted residual factors for significantly intense reflections: 0.2465
• Weighted residual factors for all reflections included in the refinement: 0.313
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No