Information card for entry 7038367

Structure parameters

• Formula: C32 H45 Ge O2 P2 Rh
• Calculated formula: C32 H45 Ge O2 P2 Rh
• SMILES: [Rh]([Ge](c1ccccc1)(c1ccccc1)c1ccccc1)([P](CC)(CC)CC)([P](CC)(CC)CC)(C#[O])C#[O]
• Title of publication: Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.
• Authors of publication: Ahrens, Theresia; Ahrens, Mike; Braun, Thomas; Braun, Beatrice; Herrmann, Roy
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 11
• Pages of publication: 4716 - 4728
• a: 17.9962 ± 0.0004 Å
• b: 10.8071 ± 0.0002 Å
• c: 18.715 ± 0.0004 Å
• α: 90°
• β: 116.882 ± 0.002°
• γ: 90°
• Cell volume: 3246.5 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0255
• Residual factor for significantly intense reflections: 0.0205
• Weighted residual factors for significantly intense reflections: 0.0489
• Weighted residual factors for all reflections included in the refinement: 0.05
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No