Information card for entry 7038368

Structure parameters

• Formula: C30 H60 F10 O4 P4 Rh2
• Calculated formula: C30 H60 F10 O4 P4 Rh2
• SMILES: C(C)[P](CC)(CC)[Rh]12([O](O1)[Rh]1([O]2O1)([P](CC)(CC)CC)([P](CC)(CC)CC)/C(=C(F)\C(F)(F)F)F)([P](CC)(CC)CC)C(=C(\F)C(F)(F)F)\F
• Title of publication: Synthesis of a rhodium(i) germyl complex: a useful tool for C-H and C-F bond activation reactions.
• Authors of publication: Ahrens, Theresia; Ahrens, Mike; Braun, Thomas; Braun, Beatrice; Herrmann, Roy
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2016
• Journal volume: 45
• Journal issue: 11
• Pages of publication: 4716 - 4728
• a: 11.5052 ± 0.0014 Å
• b: 11.7794 ± 0.0012 Å
• c: 15.3559 ± 0.0017 Å
• α: 90°
• β: 92.7 ± 0.005°
• γ: 90°
• Cell volume: 2078.8 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0235
• Residual factor for significantly intense reflections: 0.0211
• Weighted residual factors for significantly intense reflections: 0.0571
• Weighted residual factors for all reflections included in the refinement: 0.0588
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No