Information card for entry 7041989

Structure parameters

• Formula: C61 H51 O P2 Rh
• Calculated formula: C61 H51 O P2 Rh
• Title of publication: Oxidative formation of phosphinyl radicals from a trigonal pyramidal terminal phosphide Rh(i) complex, with an unusually long Rh-P bond.
• Authors of publication: Fischbach, Urs; Trincado, M.; Grützmacher, Hansjörg
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• Journal volume: 46
• Journal issue: 11
• Pages of publication: 3443 - 3448
• a: 11.5778 ± 0.0006 Å
• b: 17.6871 ± 0.001 Å
• c: 22.3777 ± 0.0012 Å
• α: 90°
• β: 101.004 ± 0.001°
• γ: 90°
• Cell volume: 4498.2 ± 0.4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0744
• Residual factor for significantly intense reflections: 0.0726
• Weighted residual factors for significantly intense reflections: 0.1518
• Weighted residual factors for all reflections included in the refinement: 0.1525
• Goodness-of-fit parameter for all reflections included in the refinement: 1.402
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No