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Information card for entry 7041990
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Coordinates | 7041990.cif |
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Original paper (by DOI) | HTML |
Common name | (trifluoromethanesulfonato)[tris(trop)phosphane]rhodium(I) |
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Formula | C46 H33 F3 O3 P Rh S |
Calculated formula | C46 H33 F3 O3 P Rh S |
SMILES | [Rh]123456([P](C7c8c([CH]1=[CH]2c1c7cccc1)cccc8)(C1c2c([CH]3=[CH]4c3c1cccc3)cccc2)C1c2c([CH]5=[CH]6c3c1cccc3)cccc2)OS(=O)(=O)C(F)(F)F |
Title of publication | Oxidative formation of phosphinyl radicals from a trigonal pyramidal terminal phosphide Rh(i) complex, with an unusually long Rh-P bond. |
Authors of publication | Fischbach, Urs; Trincado, M.; Grützmacher, Hansjörg |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2017 |
Journal volume | 46 |
Journal issue | 11 |
Pages of publication | 3443 - 3448 |
a | 13.0718 ± 0.0011 Å |
b | 18.2712 ± 0.0016 Å |
c | 15.6047 ± 0.0013 Å |
α | 90° |
β | 103.429 ± 0.001° |
γ | 90° |
Cell volume | 3625.1 ± 0.5 Å3 |
Cell temperature | 200 ± 2 K |
Ambient diffraction temperature | 200 ± 2 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0622 |
Residual factor for significantly intense reflections | 0.0397 |
Weighted residual factors for significantly intense reflections | 0.0982 |
Weighted residual factors for all reflections included in the refinement | 0.1127 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.064 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/7041990.html
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