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Information card for entry 7041991
Preview
Coordinates | 7041991.cif |
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Original paper (by DOI) | HTML |
Formula | C58 H45 Cl2 O P2 Rh |
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Calculated formula | C58 H45 Cl2 O P2 Rh |
SMILES | [Rh]123456([P](C7c8ccccc8[CH]6=[CH]2c2c7cccc2)(C2c6c([CH]1=[CH]3c1ccccc21)cccc6)C1c2c(cccc2)[CH]5=[CH]4c2c1cccc2)P(=O)(c1ccccc1)c1ccccc1.ClCCl |
Title of publication | Oxidative formation of phosphinyl radicals from a trigonal pyramidal terminal phosphide Rh(i) complex, with an unusually long Rh-P bond. |
Authors of publication | Fischbach, Urs; Trincado, M.; Grützmacher, Hansjörg |
Journal of publication | Dalton transactions (Cambridge, England : 2003) |
Year of publication | 2017 |
Journal volume | 46 |
Journal issue | 11 |
Pages of publication | 3443 - 3448 |
a | 11.5568 ± 0.0008 Å |
b | 17.6715 ± 0.0012 Å |
c | 22.3047 ± 0.0015 Å |
α | 90° |
β | 99.327 ± 0.001° |
γ | 90° |
Cell volume | 4495 ± 0.5 Å3 |
Cell temperature | 200 ± 2 K |
Ambient diffraction temperature | 200.15 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0553 |
Residual factor for significantly intense reflections | 0.0411 |
Weighted residual factors for significantly intense reflections | 0.1126 |
Weighted residual factors for all reflections included in the refinement | 0.1228 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.067 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7041991.html
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