Information card for entry 7042575

Structure parameters

• Common name: AG121
• Formula: C94 H83 Ag3 B Cl4 F4 N3 O3 P6
• Calculated formula: C94 H83 Ag3 B Cl4 F4 N3 O3 P6
• SMILES: [Ag]123[Cl]4[Ag]5([Cl]1[Ag]4([P](N([P]5(c1ccccc1)c1ccccc1)c1ccc(OC)cc1)(c1ccccc1)c1ccccc1)[P](N([P]2(c1ccccc1)c1ccccc1)c1ccc(OC)cc1)(c1ccccc1)c1ccccc1)[P](N([P]3(c1ccccc1)c1ccccc1)c1ccc(OC)cc1)(c1ccccc1)c1ccccc1.ClCCl.[B](F)(F)(F)[F-]
• Title of publication: Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity.
• Authors of publication: Ghisolfi, Alessio; Fliedel, Christophe; de Frémont, Pierre; Braunstein, Pierre
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• Journal volume: 46
• Journal issue: 17
• Pages of publication: 5571 - 5586
• a: 10.258 ± 0.0001 Å
• b: 34.9966 ± 0.0005 Å
• c: 29.4055 ± 0.0004 Å
• α: 90°
• β: 105.104 ± 0.001°
• γ: 90°
• Cell volume: 10191.8 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1276
• Residual factor for significantly intense reflections: 0.0793
• Weighted residual factors for significantly intense reflections: 0.2433
• Weighted residual factors for all reflections included in the refinement: 0.263
• Goodness-of-fit parameter for all reflections included in the refinement: 1.073
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No