Information card for entry 7042576

Structure parameters

• Common name: AG125
• Formula: C74 H78 Ag2 B2 F8 N2 O5 P4
• Calculated formula: C74 H78 Ag2 B2 F8 N2 O5 P4
• SMILES: [Ag]([P](c1ccccc1)(c1ccccc1)N([P]([Ag]1[O]2CCCC2)(c2ccccc2)c2ccccc2)c2ccc(cc2)OC)[P](c2ccccc2)(c2ccccc2)N([P]1(c1ccccc1)c1ccccc1)c1ccc(cc1)OC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-].C1CCOC1.C1OCCC1
• Title of publication: Mono- and polynuclear Ag(i) complexes of N-functionalized bis(diphenylphosphino)amine DPPA-type ligands: synthesis, solid-state structures and reactivity.
• Authors of publication: Ghisolfi, Alessio; Fliedel, Christophe; de Frémont, Pierre; Braunstein, Pierre
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• Journal volume: 46
• Journal issue: 17
• Pages of publication: 5571 - 5586
• a: 11.2883 ± 0.0002 Å
• b: 23.0676 ± 0.0004 Å
• c: 27.7279 ± 0.0003 Å
• α: 90°
• β: 101.891 ± 0.001°
• γ: 90°
• Cell volume: 7065.23 ± 0.19 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1013
• Residual factor for significantly intense reflections: 0.0621
• Weighted residual factors for significantly intense reflections: 0.1233
• Weighted residual factors for all reflections included in the refinement: 0.1352
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No