Information card for entry 7042950

Structure parameters

• Formula: C25 H38 N2 Si Te
• Calculated formula: C25 H38 N2 Si Te
• SMILES: [Te]=[Si]1([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)C1(C(=C(C(=C1C)C)C)C)C
• Title of publication: Reactivity studies of silylene [PhC(NtBu)2](C5Me5)Si - reactions with [M(COD)Cl]2 (M = Rh(i), Ir(i)), S, Se, Te, and BH3.
• Authors of publication: Kaufmann, Sebastian; Schäfer, Sebastian; Gamer, Michael T.; Roesky, Peter W.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2017
• a: 19.819 ± 0.004 Å
• b: 8.7613 ± 0.0018 Å
• c: 29.812 ± 0.006 Å
• α: 90°
• β: 91.69 ± 0.03°
• γ: 90°
• Cell volume: 5174.3 ± 1.8 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0433
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.0584
• Weighted residual factors for all reflections included in the refinement: 0.0608
• Goodness-of-fit parameter for all reflections included in the refinement: 0.898
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No