Rare-earth metal-mediated PhC[triple bond, length as m-dash]N insertion into N,N-bis(trimethylsilyl)naphthalene-1,8-diamido dianion - a synthetic approach to complexes coordinated by ansa-bridged amido-amidinato ligand.
Authors of publication
Lyubov, Dmitry M.; Cherkasov, Anton V.; Fukin, Georgy K.; Lyssenko, Konstantin A.; Rychagova, Elena A.; Ketkov, Sergey Yu; Trifonov, Alexander A.
Journal of publication
Dalton transactions (Cambridge, England : 2003)
Year of publication
2018
Journal volume
47
Journal issue
2
Pages of publication
438 - 451
a
11.4113 ± 0.0007 Å
b
27.1287 ± 0.0014 Å
c
12.0915 ± 0.0008 Å
α
90°
β
97.749 ± 0.005°
γ
90°
Cell volume
3709 ± 0.4 Å3
Cell temperature
200 ± 2 K
Ambient diffraction temperature
200 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0911
Residual factor for significantly intense reflections
0.0533
Weighted residual factors for significantly intense reflections
0.0853
Weighted residual factors for all reflections included in the refinement
0.0955
Goodness-of-fit parameter for all reflections included in the refinement
