Information card for entry 7046592

Structure parameters

• Chemical name: chloroform[[(1,2,5,6-n)-1,5-cyclooctadiene][(2-(9-borabicyclo[3.3.1]non-9-yl)ethyl]diphenylphosphine]rhodium
• Formula: C30 H40 B Cl P Rh
• Calculated formula: C30 H40 B Cl P Rh
• Title of publication: Access to a pair of ambiphilic phosphine-borane regioisomers by rhodium-catalyzed hydroboration.
• Authors of publication: Nichols, Brian R.; Akhmedov, Novruz G.; Petersen, Jeffrey L.; Popp, Brian V.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 25
• Pages of publication: 8456 - 8465
• a: 11.0741 ± 0.001 Å
• b: 11.69 ± 0.001 Å
• c: 13.0735 ± 0.0011 Å
• α: 65.811 ± 0.002°
• β: 75.634 ± 0.001°
• γ: 62.642 ± 0.001°
• Cell volume: 1367.4 ± 0.2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0604
• Residual factor for significantly intense reflections: 0.0547
• Weighted residual factors for significantly intense reflections: 0.1591
• Weighted residual factors for all reflections included in the refinement: 0.1632
• Goodness-of-fit parameter for all reflections included in the refinement: 1.098
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No