Information card for entry 7046593

Structure parameters

• Chemical name: carbonylchlorobis[(2-(9-borabicyclo[3.3.1]non-9-yl)ethyl)diphenylphosphine]rhodium
• Formula: C49 H66 B2 Cl O2 P2 Rh
• Calculated formula: C45 H56 B2 Cl O P2 Rh
• Title of publication: Access to a pair of ambiphilic phosphine-borane regioisomers by rhodium-catalyzed hydroboration.
• Authors of publication: Nichols, Brian R.; Akhmedov, Novruz G.; Petersen, Jeffrey L.; Popp, Brian V.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 25
• Pages of publication: 8456 - 8465
• a: 10.851 ± 0.001 Å
• b: 18.685 ± 0.002 Å
• c: 23.362 ± 0.002 Å
• α: 90°
• β: 97.51 ± 0.002°
• γ: 90°
• Cell volume: 4696 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0527
• Residual factor for significantly intense reflections: 0.0367
• Weighted residual factors for significantly intense reflections: 0.1025
• Weighted residual factors for all reflections included in the refinement: 0.1085
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No