Information card for entry 7046907

Structure parameters

• Formula: C63 H76 B2 N8 P2 Rh2
• Calculated formula: C63 H76 B2 N8 P2 Rh2
• Title of publication: Simple generation of a dirhodium μ-carbido complex via thiocarbonyl reduction.
• Authors of publication: Barnett, Harrison J.; Burt, Liam K.; Hill, Anthony F.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 29
• Pages of publication: 9570 - 9574
• a: 18.7605 ± 0.0007 Å
• b: 13.5447 ± 0.0006 Å
• c: 23.3266 ± 0.001 Å
• α: 90°
• β: 99.155 ± 0.004°
• γ: 90°
• Cell volume: 5851.9 ± 0.4 ų
• Cell temperature: 150 ± 0.1 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.0737
• Residual factor for significantly intense reflections: 0.0474
• Weighted residual factors for significantly intense reflections: 0.1108
• Weighted residual factors for all reflections included in the refinement: 0.1279
• Goodness-of-fit parameter for all reflections included in the refinement: 1.11
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No