Information card for entry 7046909

Structure parameters

• Formula: C49 H59 B2 N12 P Rh2
• Calculated formula: C49 H59 B2 N12 P Rh2
• Title of publication: Simple generation of a dirhodium μ-carbido complex via thiocarbonyl reduction.
• Authors of publication: Barnett, Harrison J.; Burt, Liam K.; Hill, Anthony F.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 29
• Pages of publication: 9570 - 9574
• a: 26.2284 ± 0.001 Å
• b: 10.6335 ± 0.0004 Å
• c: 38.1132 ± 0.0013 Å
• α: 90°
• β: 97.948 ± 0.004°
• γ: 90°
• Cell volume: 10527.6 ± 0.7 ų
• Cell temperature: 150.01 ± 0.1 K
• Ambient diffraction temperature: 150.01 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0932
• Residual factor for significantly intense reflections: 0.0594
• Weighted residual factors for significantly intense reflections: 0.1147
• Weighted residual factors for all reflections included in the refinement: 0.1264
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No