Information card for entry 7046916

Structure parameters

• Formula: C54 H120 Ce O17.5 Si4
• Calculated formula: C54 H120 Ce O17.5 Si4
• Title of publication: Redox-enhanced hemilability of a tris(tert-butoxy)siloxy ligand at cerium.
• Authors of publication: Friedrich, Jochen; Qiao, Yusen; Maichle-Mössmer, Cäcilia; Schelter, Eric J.; Anwander, Reiner
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2018
• Journal volume: 47
• Journal issue: 30
• Pages of publication: 10113 - 10123
• a: 14.0472 ± 0.0003 Å
• b: 14.0472 ± 0.0003 Å
• c: 66.0924 ± 0.0014 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 11294.4 ± 0.4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 145
• Hermann-Mauguin space group symbol: P 32
• Hall space group symbol: P 32
• Residual factor for all reflections: 0.0692
• Residual factor for significantly intense reflections: 0.055
• Weighted residual factors for significantly intense reflections: 0.1116
• Weighted residual factors for all reflections included in the refinement: 0.1154
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No