Information card for entry 7047229

Structure parameters

• Formula: C46 H40 Ge2 N2 O30 Rh14
• Calculated formula: C46 H40 Ge2 N2 O30 Rh14
• Title of publication: Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [Rh13Ge(CO)25]3-, [Rh14Ge2(CO)30]2- and [Rh12Ge(CO)27]4- cluster anions.
• Authors of publication: Boccalini, Alberto; Dyson, Paul; Femoni, Cristina; Iapalucci, Maria Carmela; Ruggieri, Silvia; Zacchini, Stefano
• Journal of publication: Dalton Transactions
• Year of publication: 2018
• a: 11.4246 ± 0.0004 Å
• b: 11.5375 ± 0.0004 Å
• c: 13.4617 ± 0.0005 Å
• α: 112.059 ± 0.002°
• β: 98.082 ± 0.002°
• γ: 94.045 ± 0.003°
• Cell volume: 1613.4 ± 0.1 ų
• Cell temperature: 77 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1165
• Residual factor for significantly intense reflections: 0.055
• Weighted residual factors for significantly intense reflections: 0.1143
• Weighted residual factors for all reflections included in the refinement: 0.1445
• Goodness-of-fit parameter for all reflections included in the refinement: 0.99
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No