Information card for entry 7047230

Structure parameters

• Formula: C57 H80 Br Ge N4 O25 Rh13
• Calculated formula: C57 H80 Br Ge N4 O25 Rh13
• Title of publication: Insertion of germanium atoms in high-nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [Rh13Ge(CO)25]3-, [Rh14Ge2(CO)30]2- and [Rh12Ge(CO)27]4- cluster anions.
• Authors of publication: Boccalini, Alberto; Dyson, Paul; Femoni, Cristina; Iapalucci, Maria Carmela; Ruggieri, Silvia; Zacchini, Stefano
• Journal of publication: Dalton Transactions
• Year of publication: 2018
• a: 18.5028 ± 0.0006 Å
• b: 18.5028 ± 0.0006 Å
• c: 22.8486 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7822.3 ± 0.5 ų
• Cell temperature: 77 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 130
• Hermann-Mauguin space group symbol: P 4/n c c
• Hall space group symbol: -P 4a 2ac
• Residual factor for all reflections: 0.0627
• Residual factor for significantly intense reflections: 0.0482
• Weighted residual factors for significantly intense reflections: 0.0982
• Weighted residual factors for all reflections included in the refinement: 0.1035
• Goodness-of-fit parameter for all reflections included in the refinement: 1.146
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No