Information card for entry 7048902

Structure parameters

• Formula: C59 H61 B F24 N O2 P2 Rh
• Calculated formula: C59 H61 B F24 N O2 P2 Rh
• Title of publication: A convenient method for the generation of {Rh(PNP)}⁺ and {Rh(PONOP)}⁺ fragments: reversible formation of vinylidene derivatives.
• Authors of publication: Gyton, Matthew R.; Hood, Thomas M.; Chaplin, Adrian B.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 9
• Pages of publication: 2877 - 2880
• a: 12.7701 ± 0.00019 Å
• b: 18.6612 ± 0.0002 Å
• c: 27.1605 ± 0.0004 Å
• α: 90°
• β: 95.4584 ± 0.0014°
• γ: 90°
• Cell volume: 6443.14 ± 0.15 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0621
• Residual factor for significantly intense reflections: 0.0435
• Weighted residual factors for significantly intense reflections: 0.1034
• Weighted residual factors for all reflections included in the refinement: 0.1125
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No