Information card for entry 7048904

Structure parameters

• Formula: C114 H114 B2 F48 N2 O4 P4 Rh2
• Calculated formula: C114 H114 B2 F48 N2 O4 P4 Rh2
• Title of publication: A convenient method for the generation of {Rh(PNP)}⁺ and {Rh(PONOP)}⁺ fragments: reversible formation of vinylidene derivatives.
• Authors of publication: Gyton, Matthew R.; Hood, Thomas M.; Chaplin, Adrian B.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 9
• Pages of publication: 2877 - 2880
• a: 14.7153 ± 0.0003 Å
• b: 14.7461 ± 0.0003 Å
• c: 16.7356 ± 0.0003 Å
• α: 106.475 ± 0.0019°
• β: 91.7319 ± 0.0017°
• γ: 114.793 ± 0.002°
• Cell volume: 3114.69 ± 0.13 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0476
• Residual factor for significantly intense reflections: 0.0396
• Weighted residual factors for significantly intense reflections: 0.0912
• Weighted residual factors for all reflections included in the refinement: 0.0972
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No