Information card for entry 7049037

Structure parameters

• Formula: C67 H73 B O3 Os P2
• Calculated formula: C67 H73 B O3 Os P2
• Title of publication: Pentamethylcyclopentadienyl osmium complexes that contain diazoalkane, dioxygen and allenylidene ligands: preparation and reactivity.
• Authors of publication: Albertin, Gabriele; Antoniutti, Stefano; Castro, Jesús; Sibilla, Francesca
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 9
• Pages of publication: 3116 - 3131
• a: 10.5543 ± 0.0008 Å
• b: 16.5381 ± 0.0013 Å
• c: 16.6482 ± 0.0013 Å
• α: 92.982 ± 0.003°
• β: 99.5 ± 0.003°
• γ: 94.337 ± 0.003°
• Cell volume: 2851.7 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0756
• Residual factor for significantly intense reflections: 0.0493
• Weighted residual factors for significantly intense reflections: 0.0942
• Weighted residual factors for all reflections included in the refinement: 0.1023
• Goodness-of-fit parameter for all reflections included in the refinement: 1.029
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No