Information card for entry 7051012

Structure parameters

• Common name: Bis-(Methyltropp)rhodium-hexafluorophosphate
• Formula: C58 H49 F6 N P3 Rh
• Calculated formula: C58 H49 F6 N P3 Rh
• Title of publication: Highly distorted d8-rhodium(+I) and d10-rhodium(-I) complexes: synthesis, reactivity, and structures in solution and solid state
• Authors of publication: Deblon, Stephan; Rüegger, Heinz; Schönberg, Hartmut; Loss, Sandra; Gramlich, Volker; Grützmacher, Hansjörg
• Journal of publication: New Journal of Chemistry
• Year of publication: 2001
• Journal volume: 25
• Journal issue: 1
• Pages of publication: 83
• a: 10.844 ± 0.002 Å
• b: 20.697 ± 0.004 Å
• c: 22.722 ± 0.005 Å
• α: 91.629 ± 0.013°
• β: 91.462 ± 0.013°
• γ: 101.89 ± 0.012°
• Cell volume: 4985.7 ± 1.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0706
• Residual factor for significantly intense reflections: 0.0361
• Weighted residual factors for all reflections: 0.0769
• Weighted residual factors for significantly intense reflections: 0.0721
• Goodness-of-fit parameter for all reflections: 0.751
• Goodness-of-fit parameter for significantly intense reflections: 0.964
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No