Information card for entry 7053534

Structure parameters

• Formula: C35 H49 D6 Ge N O3 Si3 W
• Calculated formula: C35 H54 Ge N O3 Si3 W
• SMILES: [W]12345([Ge]([O]=CN1c1ccccc1)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)(C#[O])(C#[O])[c]1([c]2([c]3([c]4([c]51C)C)C)C)C.c1ccccc1
• Title of publication: Reactions of a hydrido(hydrogermylene)tungsten complex with some heterocumulenes: hydrogermylation and thermal rearrangement
• Authors of publication: Hashimoto, Hisako; Fukuda, Tetsuya; Tobita, Hiromi
• Journal of publication: New Journal of Chemistry
• Year of publication: 2010
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1723
• a: 8.856 ± 0.0003 Å
• b: 13.738 ± 0.0005 Å
• c: 15.95 ± 0.0007 Å
• α: 90°
• β: 99.9596 ± 0.0018°
• γ: 90°
• Cell volume: 1911.29 ± 0.13 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0301
• Residual factor for significantly intense reflections: 0.0274
• Weighted residual factors for significantly intense reflections: 0.0748
• Weighted residual factors for all reflections included in the refinement: 0.0824
• Goodness-of-fit parameter for all reflections included in the refinement: 1.145
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No