Information card for entry 7053535

Structure parameters

• Formula: C29 H49 Ge N O2 S Si3 W
• Calculated formula: C29 H48 Ge N O2 S Si3 W
• SMILES: [W]12345([Ge](N(C=[S]1)c1ccccc1)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)(C#[O])(C#[O])[c]1([c]5([c]4([c]3([c]21C)C)C)C)C
• Title of publication: Reactions of a hydrido(hydrogermylene)tungsten complex with some heterocumulenes: hydrogermylation and thermal rearrangement
• Authors of publication: Hashimoto, Hisako; Fukuda, Tetsuya; Tobita, Hiromi
• Journal of publication: New Journal of Chemistry
• Year of publication: 2010
• Journal volume: 34
• Journal issue: 8
• Pages of publication: 1723
• a: 12.824 ± 0.0006 Å
• b: 16.7658 ± 0.0005 Å
• c: 17.575 ± 0.0006 Å
• α: 90°
• β: 108.991 ± 0.0009°
• γ: 90°
• Cell volume: 3573 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0285
• Residual factor for significantly intense reflections: 0.024
• Weighted residual factors for significantly intense reflections: 0.0746
• Weighted residual factors for all reflections included in the refinement: 0.0801
• Goodness-of-fit parameter for all reflections included in the refinement: 1.267
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No