Information card for entry 7063350

Structure parameters

• Formula: C33 H33 Cl2 F9 N3 O Si V
• Calculated formula: C33 H33 Cl2 F9 N3 O Si V
• Title of publication: Vanadium(v) arylimido alkylidene N-heterocyclic carbene complexes containing fluorinated alkoxide or halogenated phenoxide ligands for the syndiospecific ROMP of cyclic olefins
• Authors of publication: Nomura, Kotohiro; Kuwahara, Shuko; Suthala, Jirapa; Kawamoto, Yuta; Shimoyama, Daisuke; Buchmeiser, Michael R.
• Journal of publication: New Journal of Chemistry
• Year of publication: 2024
• Journal volume: 48
• Journal issue: 34
• Pages of publication: 14865 - 14872
• a: 15.1196 ± 0.0005 Å
• b: 16.0398 ± 0.0005 Å
• c: 15.517 ± 0.0005 Å
• α: 90°
• β: 102.341 ± 0.003°
• γ: 90°
• Cell volume: 3676.2 ± 0.2 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1007
• Residual factor for significantly intense reflections: 0.0818
• Weighted residual factors for significantly intense reflections: 0.2132
• Weighted residual factors for all reflections included in the refinement: 0.2234
• Goodness-of-fit parameter for all reflections included in the refinement: 1.12
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No