Information card for entry 7100137

Structure parameters

• Formula: C29 H29 Mn2 N3 O8.5 P
• Calculated formula: C29 H29 Mn2 N3 O8.5 P
• Title of publication: Reactivity of Electrophilic m2-Phosphinidene Complexes with Heterocumulenes: Formation of the First s-p-Aminophosphaimine Complexes [Mn2(CO)8{m-h1,h2-P(NiPr2)=NR}] and Diazoalkane Insertions into Metal-Phosphorus Bonds.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 12.1027 ± 0.0016 Å
• b: 20.563 ± 0.003 Å
• c: 13.6644 ± 0.0018 Å
• α: 90°
• β: 111.888 ± 0.002°
• γ: 90°
• Cell volume: 3155.5 ± 0.7 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No