Information card for entry 7100138

Structure parameters

• Formula: C39 H42 Co2 N O4 P3
• Calculated formula: C39 H42 Co2 N O4 P3
• SMILES: [Co]123([Co]([P](C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)([P]2(N1C(CCCC1(C)C)(C)C)C3)(C#[O])C#[O])(C#[O])C#[O]
• Title of publication: Reactivity of Electrophilic m2-Phosphinidene Complexes with Heterocumulenes: Formation of the First s-p-Aminophosphaimine Complexes [Mn2(CO)8{m-h1,h2-P(NiPr2)=NR}] and Diazoalkane Insertions into Metal-Phosphorus Bonds.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 30.17 ± 0.006 Å
• b: 10.6655 ± 0.0019 Å
• c: 23.493 ± 0.004 Å
• α: 90°
• β: 102.347 ± 0.003°
• γ: 90°
• Cell volume: 7385 ± 2 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No