Information card for entry 7100141

Structure parameters

• Formula: C14 H14 Mn2 N O8 P
• Calculated formula: C14 H14 Mn2 N O8 P
• SMILES: [Mn]1([Mn](P1N(C(C)C)C(C)C)(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Reactivity of Electrophilic m2-Phosphinidene Complexes with Heterocumulenes: Formation of the First s-p-Aminophosphaimine Complexes [Mn2(CO)8{m-h1,h2-P(NiPr2)=NR}] and Diazoalkane Insertions into Metal-Phosphorus Bonds.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 6.6736 ± 0.0007 Å
• b: 9.5035 ± 0.0009 Å
• c: 15.4285 ± 0.0015 Å
• α: 104.344 ± 0.002°
• β: 96.656 ± 0.002°
• γ: 97.44 ± 0.002°
• Cell volume: 928.81 ± 0.16 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No