Information card for entry 7100140

Structure parameters

• Formula: C17 H23 Mn2 N2 O8 P Si
• Calculated formula: C17 H23 Mn2 N2 O8 P Si
• SMILES: [Mn]12([Mn]([P]1(N(C(C)C)C(C)C)N2[Si](C)(C)C)(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Reactivity of Electrophilic m2-Phosphinidene Complexes with Heterocumulenes: Formation of the First s-p-Aminophosphaimine Complexes [Mn2(CO)8{m-h1,h2-P(NiPr2)=NR}] and Diazoalkane Insertions into Metal-Phosphorus Bonds.
• Authors of publication: A. Carty; Todd Graham; Konstantin A. Udachin
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 15.7307 ± 0.0013 Å
• b: 10.5029 ± 0.0008 Å
• c: 15.5917 ± 0.0013 Å
• α: 90°
• β: 113.01 ± 0.001°
• γ: 90°
• Cell volume: 2371.1 ± 0.3 ų
• Cell temperature: 125 ± 2 K
• Ambient diffraction temperature: 125 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No