Information card for entry 7100777

Structure parameters

• Formula: C42 H66 N3 O2 Si2 Sm
• Calculated formula: C42 H66 N3 O2 Si2 Sm
• SMILES: [Sm]123456789%10%11([n]%12[c]%134[cH]5[cH]%11[c]6%12C(CC)(CC)c4[o]2c(cc4)C(CC)(CC)[c]27[cH]8[cH]9[c]%10([n]12)C(CC)(CC)c1[o]3c(cc1)C%13(CC)CC)N([Si](C)(C)C)[Si](C)(C)C
• Title of publication: C-H Activation (g-deprotonation) of a Sm(III) bis(trimethylsilyl)amide complex via macrocyclic stabilisation of the sodium counter ion
• Authors of publication: Michael Guy Gardiner; Jun Wang
• Journal of publication: Chemical Communications
• Year of publication: 2005
• a: 12.1717 ± 0.0001 Å
• b: 27.7942 ± 0.0003 Å
• c: 13.6249 ± 0.0001 Å
• α: 90°
• β: 113.142 ± 0.0005°
• γ: 90°
• Cell volume: 4238.43 ± 0.07 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No