Information card for entry 7102925

Structure parameters

• Common name: (BP2)Cu(NH2Mes)
• Formula: C39 H63 B Cu N P2
• Calculated formula: C39 H63 B Cu N P2
• SMILES: [Cu]1([P](C[B](c2ccccc2)(c2ccccc2)C[P]1(C(C)(C)C)C(C)(C)C)(C(C)(C)C)C(C)(C)C)[NH2]c1c(cc(cc1C)C)C
• Title of publication: Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2).
• Authors of publication: Mankad, Neal P; Peters, Jonas C
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 9
• Pages of publication: 1061 - 1063
• a: 10.186 ± 0.005 Å
• b: 17.079 ± 0.008 Å
• c: 22.083 ± 0.007 Å
• α: 90°
• β: 98.24 ± 0.04°
• γ: 90°
• Cell volume: 3802 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1049
• Residual factor for significantly intense reflections: 0.0473
• Weighted residual factors for significantly intense reflections: 0.0746
• Weighted residual factors for all reflections included in the refinement: 0.0834
• Goodness-of-fit parameter for all reflections included in the refinement: 1.288
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No