Information card for entry 7102926

Structure parameters

• Common name: (BP2)Cu(thf)
• Formula: C34 H58 B Cu O P2
• Calculated formula: C34 H58 B Cu O P2
• SMILES: [B]1(c2ccccc2)(C[P](C(C)(C)C)([Cu]([O]2CCCC2)[P](C1)(C(C)(C)C)C(C)(C)C)C(C)(C)C)c1ccccc1
• Title of publication: Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2).
• Authors of publication: Mankad, Neal P; Peters, Jonas C
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2008
• Journal issue: 9
• Pages of publication: 1061 - 1063
• a: 17.548 ± 0.003 Å
• b: 30.333 ± 0.005 Å
• c: 12.818 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6823 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 43
• Hermann-Mauguin space group symbol: F d d 2
• Hall space group symbol: F 2 -2d
• Residual factor for all reflections: 0.0365
• Residual factor for significantly intense reflections: 0.0324
• Weighted residual factors for significantly intense reflections: 0.0798
• Weighted residual factors for all reflections included in the refinement: 0.0828
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No